Abstract

The asymmetric unit of the title compound, H5O2+·Br−·4C9H22OSi, is composed of four di-tert-butyl­methyl­silanol mol­ecules, one Br− anion, and two half H5O2+ ions, each of which has one disordered H atom. The silanol mol­ecules form hydrogen bonds to the Br anion and the H5O2+ ions form hydrogen bonds to the hydroxyl O atoms of the silanol mol­ecules.

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