Dihydrogen Complex Formation and C−C Bond Cleavage from Protonation of Cp*RuH(diene) Complexes

Guochen Jia,Chak Po Lau,Weng Sang Ng

doi:10.1021/om9805640

Dihydrogen Complex Formation and C−C Bond Cleavage from Protonation of Cp*RuH(diene) Complexes

Guochen Jia, Chak Po Lau + Show 1 more

https://doi.org/10.1021/om9805640

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Journal: Organometallics	Publication Date: Sep 19, 1998
Citations: 36

Affiliation: University of Hong Kong

#Reaction Of Cp #Protonation Of Cp + Show 7 more

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Abstract

Reaction of Cp*RuH(COD) with HBF4·OEt2 at −76 °C produced [Cp*Ru(H2)(COD)]BF4, which transformed to [Cp*Ru(η6-1,3,5-COT)]BF4 on warming to room temperature. Reaction of Cp*RuH(NBD) with HBF4·OEt2 produced a mixture of nortricyclene and the novel bimetallic complex [(Cp*Ru)2(μ-H)(μ-C5H5−CHCH2)]BF4.

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