Abstract
Pincer complexes are widely used in catalysis and activation of small molecules. We present here the synthesis and spectroscopic study of rhodium dihydrogen and dinitrogen complexes with metallocene-based P,C,P pincer ligands. Relative electron donor ability of ferrocene-, ruthenocene- and benzene-derived pincer ligands, as well as HH distance were elucidated based on JHD coupling constants and T1 relaxation time for dihydrogen complexes.
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