Abstract
A photoinduced radical difluoromethylarylation via tandem addition-cyclization of alkynes with easily available [bis(difluoroacetoxy)iodo]benzene is accomplished, providing a straightforward and practical route for the construction of difluoromethylated dibenzazepines. Various sensitive functional groups can be compatible under photoinduced conditions. Mechanism investigation reveals that this transformation is initiated by the addition of alkyne with difluoromethyl radical, generated in situ from [bis(difluoroacetoxy)iodo]benzene.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
