Diffusioosmosis of electrolyte solutions in fibrous porous media

Abstract

An analytical study is presented for the diffusioosmotic flow of an electrolyte solution in the fibrous medium constructed by an ordered array of parallel charged circular cylinders at the steady state. The prescribed electrolyte concentration gradient is constant but can be oriented arbitrarily with respect to the axes of the cylinders. The electric double layer surrounding each cylinder may have an arbitrary thickness relative to the radius of the cylinder. A unit cell model which allows for the overlap of the double layers of adjacent cylinders is employed to account for the effect of fibers on each other. The electrostatic potential distribution in the fluid phase of a cell is obtained by solving the linearized Poisson–Boltzmann equation, which applies to the case of low surface potential of the cylinders. The macroscopic electric field induced by the imposed electrolyte concentration gradient through the fluid phase in a cell is determined as a function of the radial position. A closed-form formula for the fluid velocity profile of the electrolyte solution due to the combination of electroosmotic and chemiosmotic contributions as a function of the porosity of the array of cylinders correct to the second order of their surface charge density or zeta potential is derived as the solution of a modified Navier–Stokes equation. The diffusioosmotic velocity can have more than one reversal in direction over a small range of the zeta potential. For a given electrolyte concentration gradient in a cell, the fluid flow rate does not necessarily increase with an increase in the electrokinetic radius of the cylinder, which is the cylinder radius divided by the Debye screening length. The effect of the radial distribution of the induced axial electric field in the double layer on the diffusioosmotic flow is found to be of dominant significance in most practical situations.