Abstract
We give an analytical method for finding the exact solution for the problem of electronic relaxation in solution, modelled by a particle diffusing under the influence of parabolic potential in the presence of a sink of rectangular shape. The Smoluchowski equation is used to model the diffusive motion. We have derived an analytical formula for the average rate constant in closed form. Solving Smoluchowski equation analytically with a sink of arbitrary width has been an unsolved problem and is important as a realistic model for non-radiative electronic relaxation of a molecule in solution.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
