Diffusion–reaction–dissolution–precipitation model in a heterogeneous porous medium with nonidentical diffusion coefficients: Analysis and homogenization

Abstract

We study a pore-scale model where two mobile species with different diffusion coefficients react and precipitate in the form of immobile species (crystal) on the surface of the solid parts in a porous medium. The reverse may also happen, i.e. the crystals may dissolute to give mobile species. The mathematical modeling of these processes will give rise to a coupled system of ordinary and partial differential equations. We first prove the existence of a unique nonnegative global weak solution and then upscale the model from microscale to macroscale.