Abstract

The study aims at deriving an equation for the temperature field of the specimen- vapour-gaseous envelope (VGE) – electrolyte three-phase system, followed by the calculation of the temperature distribution expression. The diffusion mechanism of carbon and nitrogen, in light of the theory of molecular diffusion, and the mechanism behind the plasma electrolytic saturation, is also discussed. In the PES process, the diffusion of carbon and nitrogen is affected by the strengthening voltage and processing time, which in turn affects the thickness and element distribution of the diffusion layer. Carbon, of which the diffusion depth ranges from 0.5 μm to 2.5 μm, is mainly distributed into the outermost layer. While the nitrogen is able to distribute throughout the diffusion layer as indicated by its several tens microns of diffusion depth. Further, the influence of process parameters on the diffusion of atoms during the strengthening process is verified experimentally.

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