Abstract

The Monte Carlo technique was used for modelling mass transport to fractal electrode surfaces under conditions of a potentiostatic pulse and linear scan voltammetry. Fractal surfaces of different fractal dimension D were constructed using the Walsh-Hadamard transform. The effects of surface geometry on the form of the current response and long-time cut-off are discussed with respect to the validity of diagnostic procedures used for the electrode kinetics on smooth electrodes.

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