Abstract
Self diffusion coefficients at 25°C for octamethylcyclotetrasiloxane in binary mixtures with benzene and carbon tetrachloride have been measured by pulsed field gradient pulsed n.m.r. A comparison is made of the diffusion data for these systems with the predictions of the Darken equation and of simple hard sphere theory expressions; neither approach gives a satisfactory representation to the data. Friction coefficients, ζ11, for octamethylcyclotetrasiloxane have been evaluated for part of the composition range.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
