Abstract
By describing the bimolecular kinetics a multiparticle problem is solved. The state of the system is described not by the mean number of particles (or concentration), but by the set of probabilities P N ( t), N=0, 1, 2, …, N 0, that the system consists of N particles. This is especially important for systems comprised of a small number of particles grouped into clusters or spurs. The probabilities P N ( t) are interrelated by balance equations. The rates of transfer of the system between states with different N depend on the spatial distribution of particles and are calculated in a biparticle approximation. The theoretical results are compared with a Monte Carlo simulation of the kinetics. The fluctuational asymptote of bimolecular kinetics at long times is also discussed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
