Abstract

A method for distinguishing between C-glycosyl compounds and O-glycosides depending on the acid stability of the borohydride reduction products of periodate-oxidized compounds has been examined and found to give equivocal results. The method can, however, be of value in determining the structure of the glycosyl residue. Examination of NMR spectra and the products of methylation have established the C-glycosyl nature of orientin and iso-orientin.

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