Abstract
The phase diagram of the binary LiCl–CaCl 2 system was investigated by differential scanning calorimetry (DSC). From the experimental results formation of a compound, LiCaCl 3 at 439±4°C is discerned. The compound undergoes peritectic decomposition at 490°C. The system shows a eutectic reaction between the compound and solid solution rich in LiCl at 485°C. Also, the system exhibits significant solid solubility of LiCl(s) in CaCl 2(s) and vice versa. The complete phase diagram of this system is constructed and reported.
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