Differential diffusion effects in the near field of non-premixed NH3/H2/N2-air jet flames at elevated pressure

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Differential diffusion (diff-diff) effects are analyzed in both non-premixed laminar and turbulent NH3-H2-N2 jet flames at 5 bar using 1D quantitative Raman scattering measurements. The two target flames feature fuel compositions simulating a 14% and a 28% NH3 cracking ratio. A diff-diff parameter is introduced for ammonia combustion, analogous to the definition used for hydrocarbon flames. Measurements in laminar flames, compared to Chemkin simulation featuring multi-component transport show that the instrument is capable of measuring the mean diff-diff parameter, but that single-shot measurements are compromised by the large sensitivity of the parameter to errors in N2 and NH3 mass fractions. The analysis of the diff-diff parameter in turbulent flames shows that both flames have strong differential diffusion in the near field up to an axial distance of 10 diameters (Z/D = 10), then the turbulent mixing becomes dominant further downstream. The flame with a 28% NH3 cracking ratio exhibits a higher diff-diff parameter especially in the low-temperature region (<1000 K) due to the higher H2 content. The competition between differential diffusion and turbulent mixing in the near field is also reflected in the NH3, H2, and NH3/H2 profiles, falling in between prediction for Le = 1 and multi-component transport. Interestingly the NH3/H2 profiles in the far field converge to a profile matching that of Le = 1, but with an increased NH3/H2 ratio, showing the persistence of the differential diffusion effects in the region dominated by turbulent mixing.