Abstract
The differential line broadening effects of relaxation reagents recently observed for the 13C spin multiplets of CD- fragments are quantitatively explained by the isotropic random field model. The non-differential line broadening observed for CD2- and CD3- fragments is also explained by the same model with the random fields uncorrelated at the different 2D sites. The absence of correlation suggests that the broadening is caused by dipolar rather than scalar interactions of the nuclei with the unpaired electrons in the paramagnetic.
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