Abstract

The condensation of acetylated 1-( endo-cyano)ethylidene derivatives having the d- gluco, d- xylo, and d- galacto configurations ( 2– 6) with a primary ( 8) and a secondary ( 9) trityl derivative was more rapid than for the corresponding exo-isomers. This difference in reactivity is explained on the basis of differences in conformation.

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