Abstract
Three new Co containing coordination polymers {Co2(suc)2(1,10′-phen)2} n (1), {Co2(glu)2(1,10′-phen)2} n (2), {Co(adip)(1,10′-phen)(H2O)} n (3), have been synthesized under the hydrothermal condition and characterized by elemental analysis, IR, TG analysis and single crystal X-ray diffraction. Complex 1 exhibits a novel two-dimensional layer framework, in which the bi-nuclear Co clusters are linked by succinic anions. Complex 2 has a one-dimensional chain-like structure. Complex 3 is also a one-dimensional chain-like structure, which is further connected by hydrogen bonds to generate a two-dimensional, layer-like structure. Furthermore, the thermal properties of the above three complexes are studied.
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