(Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN3)-1,1-diphenylethyl]-(1,2,3,3a,7a-η)-indenyl}lithium(I)

Guofeng Sun,Wanli Nie,Chong Tian,Maxim V Borzov

doi:10.1107/s1600536809011556

Guofeng Sun, Wanli Nie + Show 2 more

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https://doi.org/10.1107/s1600536809011556

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Abstract

In the title compound, [Li(C27H23N2)(C4H10O)], the Li atom possesses a nearly planar trigonal coordination environment (assuming the cyclopentadienyl ring of the indenyl group occupies one coordination place). The diethyl ether ligand adopts a nearly planar W-type conformation.

Highlights

The North-West University of Xi’an, College of Chemistry and Material Science, Taibai Bei avenue 229, Xi’an 710069, Shaanxi Province, People’s Republic of China
The authors are grateful to Mr Sun Wei for his help in measuring the NMR spectra
MVB is especially thankful to his former permanent co-author and old friend, Dr

Summary

Bruker SMART APEXII CCD diffractometer

The North-West University of Xi’an, College of Chemistry and Material Science, Taibai Bei avenue 229, Xi’an 710069, Shaanxi Province, People’s Republic of China. R factor = 0.048; wR factor = 0.152; data-to-parameter ratio = 14.4. In the title compound, [Li(C27H23N2)(C4H10O)], the Li atom possesses a nearly planar trigonal coordination environment (assuming the cyclopentadienyl ring of the indenyl group occupies one coordination place). The diethyl ether ligand adopts a nearly planar W-type conformation

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Financial support from the National Natural Science

Mo K radiation

Graphite monochromator φ and ω scans

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