Abstract
Diethanol amine-functionalized polymer-supported palladium (0) complex as catalyst for Suzuki cross-coupling reaction in water was synthesized and characterized. The catalyst exhibits excellent catalytic activity and stability in the Suzuki cross-coupling reaction. Various aryl bromides were coupled with aryl boronic acids in water, under air, and in the presence of 0.5 mol % of the catalyst to afford corresponding cross-coupled products in high yields at 100°C. Furthermore, the heterogeneous catalyst can be readily recovered by simple filtration and reused for several times only with a slight decrease in its activity. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
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