Abstract

The utility of room temperature chloroaluminate ionic liquids as solvent and catalyst for the synthetically important Diels-Alder reaction was studied. The AlCl 3-1-ethyl-3-methyl-1 H-imidazolium chloride medium proved to be ideally suited for Diels-Alder reactions. Endo selectivity and rate enhancement were observed for the cyclopentadiene/methyl acrylate Diels-Alder reaction.

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