Abstract
Rapid construction: A Diels–Alder-based approach to the synthesis of highly functionalized biaryls from readily available precursors is disclosed. The utility of these biaryl templates in palladium-mediated couplings is explored along with subsequent reductions of the nitro and phosphine oxide moieties. Finally, initial application of a synthesized biaryl as a highly active ligand in palladium-mediated coupling is carried out.
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