Abstract
AbstractThe dielectric behavior of poly(diethyl siloxane) supports the adiabatic calorimetric findings of Beatty and Karasz. In particular, a sub‐Tg transition is observed near −180°C at 100 Hz, the glass transition near −135°C at 100 Hz, and a first‐order transition near −70°C (crystal–crystal transformation). This glass‐transition temperature is the lowest reported polymeric glass transition for polymers.
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