Abstract
The nonlinear dielectric effect (NDE) has been studied in o-bromochlorobenzene and m-bromochlorobenzene, and their solutions in benzene. On the basis of NDE results and the values of electric permittivity e, density d, and refractive index n obtained in this work, the molar polarizabilities: linear (μ2 ) and nonlinear (μ 4 ) were calculated. Assuming dipolar association of the investigated dihalogenobenzenes molecules to be restricted to dimerization, the Gibbs energy ΔC0dim of the dimerization process as a function of the Onsager field factor f (e) is determined, which allowed us to draw a conclusion on the structure of associates. PACS numbers: 35.20.My, 61.25.Em, 82.60.Ik
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