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Abstract
Pure hand-block, amorphous and semi-crystalline segmented polyurethanes based on hydrogenated polybutadiene (H.PBD) were synthesized under homogenous conditions in solution. The synthesis was also realized in bulk in the case of the semi-crystalline polyurethanes. Dielectric relaxations studies were carried out to obtain better insight in the morphology of such polyurethanes and to monitor the phase separation during their synthesis.
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