Abstract
Dependences of the dielectric response spectra on the thickness of the films based on the (Ba,Sr)TiO3 (BST) solid solutions, which were deposited on single-crystal MgO substrates, have been analyzed. Using the Lorentz and Lyddane-Sachs-Teller models, the mutual correspondence of longitudinal optical (LO) and transverse optical (TO) phonon frequencies has established. The giant LO-TO splitting of the lowest-frequency vibration and inversion of LO and TO frequencies of other phonons in the IR spectrum of BST films has been found for the first time.
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