Abstract

The complex dielectric spectra of ascorbic acid solutions in pure dimethylsulfoxide (or diethylsulfoxide) and in dimethylsulfoxide (or diethylsulfoxide)/water mixtures have been measured at frequencies between 100 MHz and 20 GHz at 298.15 K. Two kinds of dielectric relaxation processes were observed in each solution. The low frequency relaxation (Debye term) is assigned to solute. The high frequency relaxation (Cole–Davidson term) is ascribed to practically unaffected solvent. From the results obtained it follows that relaxation time and relaxation strength in DESO containing solutions (i.e. binary AA/DESO and ternary AA/DESO/water systems) are greater than those in DMSO containing solutions.

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