Dielectric relaxation of sulfolane in benzene solution from microwave absorption data

Abstract

The electric constant (ɛ′) and dielectric loss (ɛ″) for dilute solutions of sulfolane in benzene solution has been measured at 9.885 GHz at different temperatures (25, 30, 35, and 40°C) by using standard microwave techniques. Following the single frequency concentration variational method, the dielectric relaxation time (τ) and dipole moment (μ) have been calculated. It is found that dielectric relaxation process can be treated as the rate process, just like the viscous flow. Based on the above studies, monomer structure of sulfolane in benzene has been inferred. The presence of solute-solvent associations in benzene solution has been proposed. Energy parameters (ΔHɛ, ΔFɛ, ΔSɛ) for dielectric relaxation process of sulfolane in benzene at 25, 30, 35, and 40°C have been calculated and compared with the corresponding energy parameters (ΔHη, ΔFη, ΔSη) for the viscous flow.