Abstract

Dielectric parameters (permittivity and loss factors) have been measured for clathrates based on ice (gas hydrates), quinol and Dianin's compound with particular attention to the frequency and temperature ranges displaying the reorientational dipole dispersion of the guest molecules. Many such processes conformed to the simple Debye form. Enthalpies (in kcal mole–1) and entropies (in cal mole–1 deg.–1) of activation for this reorientation were evaluated from Eyring's rate equation, and effective dipole moments (in D) for the guest were derived from the Böttcher-Onsager equation.[graphic omitted]

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