Abstract

Abstract The dielectric properties of completely dehydrated Rb3Na8–ZK4 zeolite were studied in the range 12–2.2×106 Hz and 211–705 K. Two kinds of losses, relaxation and conduction, were observed. The relaxation loss in the higher-frequency region had an activation energy of 99±2 kJ mol−1 and was tentatively assigned to a jump of the Rb+ ion from an 8-ring site to a vacant 4-ring site. The loss at the lower-frequency region had an activation energy of 95±3 kJ mol−1 and was attributed to a movement of the Rb+ ion on the 8-ring site beyond the unit-cell dimension.

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