Abstract
The contributions of inter-valence band (IVB) transitions to the dielectric function (DF) by free holes among the split-off (so), light-hole (lh) and heavy-hole (hh) bands were investigated. A model was developed to determine the DF of two p-type semiconductors, GaAs and Ge1−ySny with the Zinc-blend and Diamond crystal structures, respectively. The IVB transitions dominate the spectral range between 0.1–1eV with respect to the spin-orbit splittings between so-hh and lh-hh bands. In conjunction with inter-band transitions, free-carrier and lattice absorption, a complete DF model allows the determination of optical constants with improved accuracy in the spectral range covering both ultraviolet and infrared regions. The model should be applicable to most of the group III-V and IV materials since their valence band structures resemble the ones under investigation.
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