Dielectric behavior of Bi–Fe3O4 nanocomposite and Fe3O4 nanoparticles prepared via mechanochemical processing

Abstract

Bi–Fe3O4 nanocomposite and Fe3O4 nanoparticles were prepared via mechanochemical processing. Structural, compositional, and morphological characterizations of products were carried out by using X-ray diffraction, Scanning electron microscopy and Transmission electron microscopy. The investigation of dielectric constant (ε′), dielectric loss tangent (tanδ), and AC resistivity was carried out in an applied field with frequency range of 100–1MHz and at temperatures from 79 to 300K. The variation of DC electrical resistivity with temperature was investigated with a two probe method from 79 to 300K. It was found that ε′and tanδ decrease with increasing frequency and temperature. The DC resistivity decreases with increasing temperature. The experimental results show that both AC and DC resistivity, dielectric constants and activation energy of Bi–Fe3O4 nanocomposite are larger than those related to Fe3O4 and tanδ of the composite is much lower than that of Fe3O4.