Abstract

Low frequency dielectric studies in the temperature range 80–500 K were performed on the solid solution derived from BaTiO 3, Ba 1−3 a Bi 2 a TiO 3 with 0< a<0.117. The temperature and frequency variations of the real part of the relative permittivity show two different behaviors, depending upon the substitution rate. A classical ferroelectric behavior was observed for a varying approximately from 0 to 0.03. However, a relaxor behavior appears for higher values of a. The replacement of Ba 2+ by Bi 3+ in the A site shows a remarkable decrease of T C. The dielectric studies were confirmed by pyroelectric study.

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