Abstract

Dielectric and pressure virial coefficients of SF6 have been determined at 323.3, 348.3, and 373.9 K. Attributing the temperature dependent contribution of the second dielectric virial coefficient to dipole moments induced in one molecule by the hexadecapole moment of a second gives (5.40±0.7)×10−41 esu · cm4 for the molecular hexadecapole moment of SF6. The hexadecapole moment of SF6 derived from pressure second virial coefficients is (5.75±0.3)×10−41 esu · cm4.

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