Abstract

The development of carbon nanotubes based materials has been impeded by both their difficult dispersion in the polymer matrix and their high cost. The discovery of graphene and the subsequent development of graphene-based polymer nanocomposites is an important addition in the area of nanoscience and technology. In this study the influence of graphene nanoparticles (GNP) in concentrations from 2.0 to 10.0 phr on the dielectric (dielectric permittivity, dielectric loss angle tangent) and microwave (reflection coefficient, attenuation coefficient, shielding effectiveness) properties of nanocomposites on the basis of natural rubber has been investigated in the wide frequency range (1 - 12 GHz). The results achieved allow recommending graphene as a filler for natural rubber based composites to afford specific dielectric and microwave properties, especially when their loading with the much more expensive carbon nanotubes is not possible.

Highlights

  • Over the past five decades, industrial scale “composite materials” have been produced by adding different minerals and metals to thermosetting, thermoplastic and elastomeric polymers

  • In this study the influence of graphene nanoparticles (GNP) in concentrations from 2.0 to 10.0 phr on the dielectric and microwave properties of nanocomposites on the basis of natural rubber has been investigated in the wide frequency range (1 - 12 GHz)

  • 1) The effect that graphene nanoparticles have upon the dielectric and microwave properties of natural rubber based composites filled at 2.0 up to 10.0 phr has been studied in the 1 - 12 GHz range

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Summary

Introduction

Over the past five decades, industrial scale “composite materials” have been produced by adding different minerals and metals to thermosetting, thermoplastic and elastomeric polymers. Electrons shoot along with minimal resistance which may allow for low-power, fasterswitching transistor and become a candidate to replace silicon in the area of microchip electronics All these unique properties in a single nanomaterial have made physicists, chemists and material scientists exited about graphene’s potential. Neither there are available reports on investigations on those properties carried out in a wider frequency range, first of all at frequencies lower than 8 GHz. the aim of this work is to study the influence that graphene nanoparticles (in amounts of 2 to 10 phr) have on the dielectric (dielectric permittivity, dielectric loss angle tangent) as well as on the microwave properties (absorption and reflection of the electromagnetic waves, the effectiveness of the electromagnetic shielding) of natural rubber based composites in a significantly greater frequency range—from 1 to 12 GHz

Characterisation of the Graphene Used
Prepapation and Vulcanization of Rubber Compounds
Microwave Properties
Complex Permittivity
Dielectric Properties
Conclusions
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