Dielectric and microwave absorption properties of Ti3SiC2/cordierite composite ceramics oxidized at high temperature

Abstract

The oxidation behavior of the bulk Ti3SiC2/cordierite composite ceramics containing 15wt.% Ti3SiC2 are investigated in air. The results demonstrate the ceramic displays excellent oxidation resistance at 800–1000°C, and the oxidation kinetics basically obey a parabolic rate law. As revealed by XRD and SEM/EDS, the oxidation scales mainly consist of rutile TiO2 and amorphous SiO2. The dielectric and microwave absorption properties of the ceramics oxidized at high temperature are also studied. Both the real and imaginary part of the complex permittivity are decreased as the oxidation temperature increases from 800 to 1000°C, which is attributed to the oxidation of Ti3SiC2 fillers close to the surface. At a given temperature, the complex permittivity decreases at the initial oxidation stage while it keeps stable as the oxidation time increases. Although the complex permittivity of the ceramics are decreased after oxidation at high temperature, the microwave absorption performances are still favorable. The results indicate the Ti3SiC2/cordierite ceramics are potential microwave absorption materials for high temperature application.