Abstract

Copper single crystals (diameter: 5–10 mm, length: 10 cm) were grown by the Czochralski method. The crystals were free from dislocations, when they were grown under optimal conditions: [100]-growth direction, high vacuum and medium pulling speed (6 cm/h). Lattice defects were caused by the following unfavourable growth conditions: (a) when grown with [110]-orientation of the growth direction or grown under hydrogen the crystals contain subgrains, (b) growth under impure Ar caused prismatic loops around Cu2O-particles and (c) micro-segregation caused by a high pulling speed.In the dislocation-free copper single crystals three kinds of defects were observed: (a) vacancy-clusters (volume density: 106 cm−3), (2) voids (∼ 105 cm−3, (3) a kind of defect not identified till now, which generates holes on the surfaces of the crystal samples when they are electropolished.

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