Abstract
Reaction of Alkali Metal Phosphides with White Phosphorus, II. Formation and Structure of 2-Lithio-2,3-dihydro-1,3-diphenyl-1H-benzotriphosphole2) The o-phenylenebis(lithium phosphide) 1 leads to a disproportionation of white phosphorus by formally taking up P+ and leaving P73−. The resultant title compound 2 may be converted to different derivatives 3 by reaction with electrophiles. According to a crystal structure analysis 2 (THF)3 consists of isolated ion pairs with Li singly coordinated to the central phosphorus.
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