Abstract
Abstract [Mn(CH3CN)6][MnI4] crystallizes from acetonitrile solutions of Mnl2 as yellow single crystals which were characterized by their IR spectrum and by a crystal-structure analysis. Space group P21/n, Z = 4, structure solution with 3742 observed unique reflections with Fo >5σ(Fo), R = 0.050. Lattice dim ensions at 20°C: a = 1258.0(5), b = 1244.7(2), c = 1753.3(6) pm, β = 92.22(3)°. The compound forms octahedral cations [Mn(CH3CN)6]2+ with site symmetry Ci with average Mn-N bond lengths of 222.3 pm and tetrahedral anions [Mnl4]2- without symmetry with average bond lengths MnI of 271.3 pm.
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