Abstract
Abstract Cesium-strontium-triazide crystallizes monoclinic, a = 917.4(l)pm, b = 1017.3(6)pm, c = 900.8pm, β = 120.15°, N = 4, space group C2/c. The crystal structure has been determined by means of single crystal X-ray data (647 independent counter reflections, 21 unobserved). The positions of the cesium and strontium ions have been found by Patterson synthesis, those of the nitrogen atoms by Fourier methods. The structure was refined by least squares calculations to a final R-value of 0.042. The heavy atoms are surrounded by eight azide groups, both coordination polyhedra form nonregular antiprisms. The azide groups are all linear and symmetric with N–N distances of 118(l)pm.
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