Die Koordinationszahl von Lanthaniden: Thermodynamik der LnIIIEDTA‐Mischkomplexe mit den Anionen der 8‐Hydroxychinolin‐5‐sulfonsäure, Iminodiessigsäure und Nitrilotriessigsäure

Abstract

AbstractThe values of ΔG, ΔH and ΔS for the formation of the mixed 1:1:1 lanthanide EDTA complexes with the anions of 8‐hydroxyquinoline‐5‐sulfonic acid, iminodiacetic acid and nitrilotriacetic acid were determined by pH‐titrations and a direct calorimetric method. These thermodynamic data are discussed and compared with those for the formation of the Ln(III)EDTA complexes. Contrary to current opinion it is concluded that all trivalent lanthanide aquoions have the same coordination number in dilute solution. However, in the series of the lanthanide EDTA complexes the coordination number changes between Sm and Tb. In this region, equilibria occur between two types of EDTA complexes with different numbers of coordinated water molecules: equation image The corresponding equilibrium constants could be evaluated. The coordination number changes also in many other Ln complexes along the lanthanide series, and similar equilibria occur.