Abstract
The transition probabilities of spin-forbidden processes become much more enhanced in the case of aza-aromatic systems than for structurally related aromatic hydrocarbons when AgNO3 is used as an external heavy atom perturber. This is explained with the strong electron donor properties of aza-aromatic systems thus causing strong interaction between the π-electronic system and the perturber. Since carbazoles are weaker electron donors than aza-aromatic systems, the enhancement of the phosphorescence/fluorescence quantum yield ratio by AgNO3 is lower than for aza-aromatic systems. The different behaviour of aza-aromatic systems and aromatic hydrocarbons in the heavy atom experiment with AgNO3 can find applications in fluorescence analysis.
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