Abstract
The five-coordinate Sn atom in the title mixed organyl stannate compound, (C12H24N)[Sn(C5H9)(C6H5)2(C2ClF2O2)], is in a trans-C3SnO2 trigonal–bipyramidal coordination environment. The NH2 groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains. One of the phenyl rings is disordered over two sites with equal occupancies.
Highlights
The five-coordinate Sn atom in the title mixed organyl stannate compound, (C12H24N)[Sn(C5H9)(C6H5)2(C2ClF2O2)], is in a trans-C3SnO2 trigonal–bipyramidal coordination environment
One of the phenyl rings is disordered over two sites with equal occupancies
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH2611)
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.010 A; disorder in main residue; R factor = 0.050; wR factor = 0.133; data-to-parameter ratio = 18.6. The five-coordinate Sn atom in the title mixed organyl stannate compound, (C12H24N)[Sn(C5H9)(C6H5)2(C2ClF2O2)], is in a trans-C3SnO2 trigonal–bipyramidal coordination environment. The NH2 groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains. One of the phenyl rings is disordered over two sites with equal occupancies. Related literature For details of the crystal structure of dicyclohexylammonium bis(chlorodifluoroacetato)cyclohexyldiphenylstannate(IV), see Teo et al (2008). For a review of the structural chemistry of organotin carboxylates, see: Tiekink (1991, 1994)
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