Abstract

Using the recently detected intense UV absorption spectrum of SiCl 2(X̃ 1A 1) the absolute rate constant has been measured for its reaction with oxygen. The value of the bimolecular rate constant, k(SiCl 2 + O 2), is equal to (3.4 ± 0.7) × 10 9 M −1 s −1 at 25° C.

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