Abstract

[4885-02-3] C2H4Cl2O (MW 114.96) InChI = 1S/C2H4Cl2O/c1-5-2(3)4/h2H,1H3 InChIKey = GRTGGSXWHGKRSB-UHFFFAOYSA-N (carbon monoxide equivalent in reactions with boranes and borinates; formylating reagent for aromatic compounds and vinylsilanes; formation of α-keto acid chlorides) Alternate Name: dichloromethoxymethane; DCME. Physical Data: bp 85 °C; d 1.271 g cm−3. Solubility: sol in most common organic solvents. Form Supplied in: commercially available in 98% purity. Preparative Methods: from Methyl Formate and Phosphorus(V) Chloride.1 Purification: by distillation. Handling, Storage, and Precaution: dichloromethyl methyl ether is moisture sensitive, a lachrymator, and a suspect carcinogen. Handle in a fume hood.

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