Abstract
The title compound, [Ru(C10H14)Cl2(C18H15P)], crystallizes with two molecules in the asymmetric unit. It adopts the classic pseudo-tetrahedral piano-stool structure. A comparison of the Ru—P, Ru—Cl, Ru—C(av) bond lengths and the sum of the P—Ru—Cl1, P—Ru—Cl2 and Cl1—Ru—Cl2 angles (for both independent molecules) with those of previously determined compounds [(η6-arene)Ru(PPh3)Cl2] reveals that the nature of the η6-arene ligand has a marginal effect on these structural parameters.
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