Abstract

In the title complex, [CoCl2(C7H6N2S4)], 2,2′-(methylenedithio)bi-1,3-thiazole acts as a bidentate ligand and chelates one CoII ion through the two N atoms to give an eight-membered symmetric unit. The CoII ion is located on a twofold axis and displays a slightly distorted tetrahedral coordination environment, where the two Cl− anions occupy the remaining coordination sites. The N—Co—N and Cl—Co—Cl planes are nearly perpendicular, with a dihedral angle of 88.0 (3)°.

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