Abstract
The title tetranuclear SnIV compound, [Sn4(C7H6Cl)8Cl2O2(OH)2], has site symmetry . Two O2− and two OH− anions bridge four SnIV cations to form the tetranuclear compound. The two independent SnIV cations assume SnO3C2 and SnO2C2Cl distorted trigonal-bipyramidal coordination geometries. Intramolecular O—H⋯Cl hydrogen bonding is present in the structure. One Cl atom of a chlorobenzyl ligand is disordered over two sites with an occupancy ratio of 0.693 (2):0.307 (2).
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.009 A; disorder in main residue; R factor = 0.029; wR factor = 0.074; data-to-parameter ratio = 15.1. Crystal data [Sn4(C7H6Cl)8Cl2O2(OH)2] Mr = 1616.22 Triclinic, P1 a = 10.986 (2) Ab = 11.227 (2) Ac = 13.573 (3) A = 74.656 (2) = 67.942 (2)
The title tetranuclear SnIV compound, [Sn4(C7H6Cl)8Cl2O2(OH)2], has site symmetry 1
The two independent SnIV cations assume SnO3C2 and SnO2C2Cl distorted trigonal-bipyramidal coordination geometries
Summary
Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.009 A; disorder in main residue; R factor = 0.029; wR factor = 0.074; data-to-parameter ratio = 15.1. Crystal data [Sn4(C7H6Cl)8Cl2O2(OH)2] Mr = 1616.22 Triclinic, P1 a = 10.986 (2) Ab = 11.227 (2) Ac = 13.573 (3) A = 74.656 (2) = 67.942 (2)
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