Abstract
The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-molecules in the asymmetric unit. Both molecules are completed by inversion symmetry with the two SnIV atoms located on inversion centers. The metal atoms have distorted octahedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thiourea S atoms. In the crystal, molecules are linked via N—H⋯Cl and N—H⋯S hydrogen bonds, forming a three-dimensional structure.
Highlights
The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-molecules in the asymmetric unit. Both molecules are completed by inversion symmetry with the two SnIV atoms located on inversion centers
The metal atoms have distorted octahedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thiourea S atoms
Molecules are linked via N—
Summary
Rint = 0.058 a Laboratoire de Chimie Minerale et Analytique, Departement de Chimie, Faculte des Sciences et Techniques, Universite Cheikh Anta Diop, Dakar, Senegal, bSchool of Chemistry, Molecular Sciences Institute, University of the Witwatersrand, Private Bag. 3, Wits 2050, Johannesburg, South Africa, and cInstitute of Physics, University of Neuchâtel, Rue Emile-Argand 11, CH-2000 Neuchâtel, Switzerland. R factor = 0.021; wR factor = 0.053; data-to-parameter ratio = 20.8. The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-molecules in the asymmetric unit. Both molecules are completed by inversion symmetry with the two SnIV atoms located on inversion centers. The metal atoms have distorted octahedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thiourea S atoms. H Cl and N—H S hydrogen bonds, forming a threedimensional structure
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