Abstract

In the structure of the title compound, [CoCl2(C9H16N2Si)2], the CoII atom is located on an inversion center in a slightly distorted tetra­hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl­silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N—H⋯Cl hydrogen bonds.

Highlights

  • In the structure of the title compound, [CoCl2(C9H16N2Si)2], the CoII atom is located on an inversion center in a slightly distorted tetrahedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2[(trimethylsilyl)amino]pyridine ligands

  • R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger

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Summary

Bruker SMART APEX CCD areadetector diffractometer

R factor = 0.033; wR factor = 0.089; data-to-parameter ratio = 17.5. In the structure of the title compound, [CoCl2(C9H16N2Si)2], the CoII atom is located on an inversion center in a slightly distorted tetrahedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2[(trimethylsilyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)

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