Abstract

In the title compound, [RuCl2(C7H8)(C21H21O3P)], the RuII atom possesses a pseudo-octa­hedral geometry and the metrical parameters around the metallic core compare well with those of similar three-legged-piano-stool complexes.

Highlights

  • In the title compound, [RuCl2(C7H8)(C21H21O3P)], the RuII atom possesses a pseudo-octahedral geometry and the metrical parameters around the metallic core compare well with those of similar three-legged-piano-stool complexes

  • Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: DN2314)

  • The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry

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Summary

Structure Reports Online

Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.006 A; R factor = 0.032; wR factor = 0.074; data-to-parameter ratio = 18.4. In the title compound, [RuCl2(C7H8)(C21H21O3P)], the RuII atom possesses a pseudo-octahedral geometry and the metrical parameters around the metallic core compare well with those of similar three-legged-piano-stool complexes. Related literature For related literature, see: Elsegood & Tocher (1995); Hafner et al (1997); Hansen & Nelson (2000); Therrien et al (2004); Eapen & Tamborski (1980); Winkhaus & Singer (1967); Zhang et al (2006). Crystal data [RuCl2(C7H8)(C21H21O3P)] Mr = 616.45 Orthorhombic, Pna a = 22.1789 (2) Ab = 8.0564 (1) Ac = 14.9717 (2) A

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